The Earth's surface and the clouds absorb visible and invisible radiation from the sun and re-emit much of the energy as infrared back to the atmosphere. Certain substances in the atmosphere, chiefly cloud droplets and water vapor, but also carbon dioxide, methane, nitrous oxide, sulfur hexafluoride, and chlorofluorocarbons absorb this infrared, and re-radiate it in all directions including back to Earth. Thus the greenhouse effect keeps the atmosphere and surface much warmer than if the infrared absorbers were absent from the atmosphere.
Greenhouse gases in the atmosphere
Recent increases in atmospheric carbon dioxide (CO2). The monthly CO2 measurements display small seasonal oscillations in an overall yearly uptrend; each year's maximum is reached during the northern hemisphere's late spring, and declines during the northern hemisphere growing season as plants remove some CO2 from the atmosphere.
Recent increases in atmospheric carbon dioxide (CO2). The monthly CO2 measurements display small seasonal oscillations in an overall yearly uptrend; each year's maximum is reached during the northern hemisphere's late spring, and declines during the northern hemisphere growing season as plants remove some CO2 from the atmosphere.
The greenhouse effect was discovered by Joseph Fourier in 1824 and was first investigated quantitatively by Svante Arrhenius in 1896. It is the process by which absorption and emission of infrared radiation by atmospheric gases warms a planet's atmosphere and surface.
Existence of the greenhouse effect as such is not disputed. Naturally occurring greenhouse gases have a mean warming effect of about 30 °C (54 °F), without which Earth would be uninhabitable. The debate centers on how the strength of the greenhouse effect is changed when human activity increases the atmospheric concentrations of some greenhouse gases.
On Earth, the major natural greenhouse gases are water vapor, which causes about 36–70% of the greenhouse effect (not including clouds); carbon dioxide (CO2), which causes 9–26%; methane (CH4), which causes 4–9%; and ozone, which causes 3–7%.[16][17] Some other naturally occurring gases contribute very small fractions of the greenhouse effect; one of these, nitrous oxide (N2O), is increasing in concentration owing to human activity such as agriculture. The atmospheric concentrations of CO2 and methane have increased by 31% and 149% respectively above pre-industrial levels since 1750. These levels are considerably higher than at any time during the last 650,000 years, the period for which reliable data has been extracted from ice cores. From less direct geological evidence it is believed that CO2 values this high were last attained 20 million years ago.[18] Fossil fuel burning has produced about three-quarters of the increase in CO2 from human activity over the past 20 years. Most of the rest is due to land-use change, in particular deforestation.
The present atmospheric concentration of CO2 is about 383 parts per million (ppm) by volume.[20] Future CO2 levels are expected to rise due to ongoing burning of fossil fuels and land-use change. The rate of rise will depend on uncertain economic, sociological, technological, and natural developments, but may be ultimately limited by the availability of fossil fuels. The IPCC Special Report on Emissions Scenarios gives a wide range of future CO2 scenarios, ranging from 541 to 970 ppm by the year 2100.[21] Fossil fuel reserves are sufficient to reach this level and continue emissions past 2100, if coal, tar sands or methane clathrates are extensively used.
Positive (reinforcing) feedback effects such as the expected release of methane from the melting of permafrost peat bogs in Siberia (possibly up to 70,000 million tonnes) may lead to significant additional sources of greenhouse gas emissions[23] not included in climate models cited by the IPCC.
Feedbacks
The effects of forcing agents on the climate are complicated by various feedback processes.
One of the most pronounced feedback effects relates to the evaporation of water. In the case of warming by the addition of long-lived greenhouse gases such as CO2, the initial warming will cause more water to be evaporated into the atmosphere. Since water vapor itself acts as a greenhouse gas, this causes still more warming; the warming causes more water vapor to be evaporated, and so forth until a new dynamic equilibrium concentration of water vapor is reached with a much larger greenhouse effect than that due to CO2 alone. (Although this feedback process involves an increase in the absolute moisture content of the air, the relative humidity stays nearly constant or even decreases slightly because the air is warmer.) This feedback effect can only be reversed slowly as CO2 has a long average atmospheric lifetime.
Feedback effects due to clouds are an area of ongoing research. Seen from below, clouds emit infrared radiation back to the surface, and so exert a warming effect. Seen from above, the same clouds reflect sunlight and emit infrared radiation to space, and so exert a cooling effect. Whether the net effect is warming or cooling depends on details such as the type and altitude of the cloud. These details are difficult to represent in climate models, in part because clouds are much smaller than the spacing between points on the computational grids of climate models (about 125 to 500 km for models used in the IPCC Fourth Assessment Report). Nevertheless, cloud feedback is second only to water vapor feedback and is positive in all the models that were used in the IPCC Fourth Assessment Report.
Another important feedback process is ice-albedo feedback.[25] When global temperatures increase, ice near the poles melts at an increasing rate. As the ice melts, land or open water takes its place. Both land and open water are on average less reflective than ice, and thus absorb more solar radiation. This causes more warming, which in turn causes more melting, and this cycle continues.
Positive feedback due to release of CO2 and CH4 from thawing permafrost is an additional mechanism contributing to warming. Possible positive feedback due to CH4 release from melting seabed ices is a further mechanism to be considered.
The ocean's ability to sequester carbon is expected to decline as it warms, because the resulting low nutrient levels of the mesopelagic zone limits the growth of diatoms in favour of smaller phytoplankton that are poorer biological pumps of carbon.
